application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols
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abstract
a direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. the method involves preparation of ionic liquid-based iminium chloride intermediate from dmf-like ionic liquid then stirring it with alcohol in present of sodium iodide. the higher yields of alkyl iodides were obtained within minimum time with simplest operational procedure. the dmf-like ionic liquids could be recycled.
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Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols
A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained w...
full textApplication of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols
A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained w...
full textSpotlight- Tetranitromethane: As a multipurpose reagent
Saeed Baghery was born in Amol/Mazandaran (Iran) in 1985. He completed his B.Sc. in Pure chemistry in 2009 from Islamic Azad University of Amol, Mazandaran, Iran. He was graduated from M.Sc. degree under the supervision of Dr. Seyed Mohammad Vahdat in Organic Chemistry from Islamic Azad University of Amol, Mazandaran, Iran. He is currently Organic Chemistry Ph.D student under the supervision of...
full textSpotlight- Tetranitromethane: As a multipurpose reagent
Saeed Baghery was born in Amol/Mazandaran (Iran) in 1985. He completed his B.Sc. in Pure chemistry in 2009 from Islamic Azad University of Amol, Mazandaran, Iran. He was graduated from M.Sc. degree under the supervision of Dr. Seyed Mohammad Vahdat in Organic Chemistry from Islamic Azad University of Amol, Mazandaran, Iran. He is currently Organic Chemistry Ph.D student under the supervision of...
full textDicationic Ionic Liquid as the Recyclable Catalyst for the Synthesis of Quinoxaline Derivatives
An efficient and eco-friendly protocol for the synthesis of quinoxaline derivatives employing a condensation reaction between 1,2-diketone and 1,2-diaminobenzene derivative has been developed. The reaction of 1,2-diketone and 1,2-diaminobenzene derivative was carried out in water at room temperature using 10 mol% of task-specific dicationic ionic liquid as a catalyst. The results show that...
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Journal title:
iranian journal of catalysisPublisher: islamic azad university, shahreza branch
ISSN 2252-0236
volume 1
issue 2 2011
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